محبوبترین نویسندگان :
نویسندگان مقالات پربازدید :
کاتالیزور کاربردی a: عمومی 2012
جزئیات رویداد
اینستاگرام تی پی بین
همایش ، رویداد ، ژورنال
حوزه های تحت پوشش رویداد

  • effective gold catalyst supported on mesoporous silica decorated by ceria for the synthesis of high value lactobionic acid

    نویسندگان :
    کلمات کلیدی :
    جزئیات بیشتر مقاله
    • تاریخ ارائه: 1392/07/24
    • تاریخ انتشار در تی پی بین: 1392/07/24
    • تعداد بازدید: 1239
    • تعداد پرسش و پاسخ ها: 0
    • شماره تماس دبیرخانه رویداد: -
     gold supported on mesoporous sba-15 and sba-15-ceo2 with ce/si molar ratios of 0.1, 0.2, 0.4 and 0.6 were synthesized via wet chemical process using a gold cationic complex precursor [au(en)2]3+(en = ethylenediamine), and investigated as catalysts for the partial oxidation of lactose to selectively synthesize lactobionic acid (lba) for therapeutic, pharmaceutical and food grad applications. these catalysts were characterized by n2 physisorption, xrd, ft-ir, tem and xps. n2 physisorption and xrd analysis revealed that sba-15-ceo2 with the investigated ce/si molar ratios support possess ordered hexagonal mesoporous structure, characterized with a high surface area and large pore volume, similar to sba-15, whereas bet surface area and pore volume of catalyst were significantly decreased upon impregnation. xps analysis revealed the coexistence of metallic and oxidized gold species (au0, au+ and au3+) in all prepared catalysts and the presence of both ce3+ and ce4+ oxidation states for gold supported on mesoporous sba-15-ceo2 catalysts. the influence of the ph value on lactose conversion was also investigated. after 60 min of reaction, the 0.7%au/sba-15-ceo2 (ce/si = 0.1 and 0.2) catalysts showed high catalytic activity (100% lactose conversion) and a 100% selectivity towards lba, when they were used at a catalyst/lactose ratio of 0.2, under alkaline (ph 9.0) and mild reaction temperature (65 °c). at the optimized conditions, 0.7% au/sba-15-ceo2 catalysts with ce/si of 0.1, 0.2 and 0.4 were more active than 0.7% au/sba-15 catalyst. a maximum of activity is reached at ce/si of 0.2. the experimental catalytic tests and characterizations show clearly the role of ce in the enhancement in the catalyst activity was the coordination and agglomeration states of ce atoms could have an important effect.

سوال خود را در مورد این مقاله مطرح نمایید :

با انتخاب دکمه ثبت پرسش، موافقت خود را با قوانین انتشار محتوا در وبسایت تی پی بین اعلام می کنم
مقالات جدیدترین رویدادها
مقالات جدیدترین ژورنال ها