محبوبترین نویسندگان :
نویسندگان مقالات پربازدید :
کاتالیزور کاربردی a: عمومی 2012
جزئیات رویداد
اینستاگرام تی پی بین
همایش ، رویداد ، ژورنال
حوزه های تحت پوشش رویداد

  • synthesis of ethyl octyl ether from diethyl carbonate and 1-octanol over solid catalysts. a screening study

    نویسندگان :
    کلمات کلیدی :
    جزئیات بیشتر مقاله
    • تاریخ ارائه: 1392/07/24
    • تاریخ انتشار در تی پی بین: 1392/07/24
    • تعداد بازدید: 1208
    • تعداد پرسش و پاسخ ها: 0
    • شماره تماس دبیرخانه رویداد: -
     the synthesis of ethyl octyl ether (eoe) from a mixture of diethyl carbonate (dec) and 1-octanol (1:2 molar ratio) over several solid catalysts was studied in batch mode at 150 °c and 25 bar. catalyst screening revealed that eoe could be successfully obtained over some acid catalysts. in particular the highest yield was achieved over acid ion-exchange resins (33% after 8 h). a reaction scheme of the process is proposed. selectivity to eoe was mainly affected by the production of diethyl ether (dee) and di-n-octyl ether (dnoe). however, eoe was the main ether obtained (60 mol%), followed by dee (20 mol%) and dnoe (20 mol%). by comparing the behavior of several acid resins, it was seen that the synthesis of eoe was highly related to the structural resin properties. it was found that the accessibility of dec and 1-octanol to acid centers was improved over highly swollen and low polymer density resins. thus, gel-type resins with low divinylbenzene content are the most suitable to produce eoe (e.g., amberlyst 121, dowex® 50wx2-100 and ct224).

سوال خود را در مورد این مقاله مطرح نمایید :

با انتخاب دکمه ثبت پرسش، موافقت خود را با قوانین انتشار محتوا در وبسایت تی پی بین اعلام می کنم
مقالات جدیدترین رویدادها
مقالات جدیدترین ژورنال ها